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Spatial Distribution of Some Alkali and Alkaline Earth Metals of Selected Locations in Sulaimani Governorate, Kurdistan Region, Iraq.


Salih N. Majid and Shuela M. Sheikh-Abdullah

Faculty of Agricultural Science-Sulaimani University, Bakrajo Street, Sulaimani -Iraq

DOI: https://doi.org/10.17656/jzs.10615

Abstract

This study aimed to determine the background concentration and also to assess the distribution pattern of some alkali metals (Na and K) and alkaline earth metals of (Mg, Ca, Be, Sr and Ba) along depth increments (0 to 15 and 15 to 30 cm) of soils from ten (10) locations in Sulaimani Governorate- KRI. The soil samples were digested by aqua regia and then analyzed by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). The results were statistically analyzed through both principal component analysis (PCA) and cluster analysis to show the similarity and dissimilarity of the soils among the studied locations.
The results showed that there was no consistent distribution pattern for the studied metal along the selected depths due to the variation of the input sources of the metals and their quantities in the parent materials and/ or to continuous mixing by agricultural operations. It was also found that the contents of the studied metals based on the highest concentration, followed the following sequence Ca > Mg > K > Ba >Sr > Na > Be. According to the results of PCA analysis, the explained variation for two factors accounted for % 60.25 of the total variance. On the other hand, the agglomerative hierarchical clustering classified the soils of the ten locations into four major groups at a significant dissimilarity percent of about 57%.


Key Words:
Agglomerative Hierarchical Clustering (AHC), Alkaline earth metals, Alkali metal, principal component analysis (PCA). Sulaimani Governorate


Refeerences


[1] Kabata-Pendias, A. and Pendias, H. "Trace Elements in Soils and Plants", Third Edition. By CRC Press LLC. Boca Raton London New York Washington, D.C. (2001).

[2] Bakšić, D., Pernar, N., Perkovic, I., Vrbek, B. and Roje, V. "Distribution of alkali earth metals and alkali metals (Ca, Mg, K, Na) in the forest soil of Medvednica Nature Park", Izvorni znanstveni članci – Original scientific papers. UDK 630*114.2 (001). Šumarski list, 1-2, pp.7-20, (2015).

[3] Halka, M. and Brian Nordstrom, B. "Periodic table of the elements-Alkali & Alkaline Earth Metals", Library of Congress Cataloging-in-Publication Data- ISBN 978-1-4381-3184-9 (e-book). Printed in the USA. (2010).

[4] Whitten, K. W., Davis, R. E., Peck, M. L., and Stanley, G. G. "General Chemistry", Seventh Edition. Thomson- Brooks/cool. Australia. Canada. United Kingdom. United State. (2004).

[5] Krebs, R. E. "The History and Use of Our Earth's Chemical Elements: A Reference Guide", Second Edition. Westport, Conn.: Greenwood Press. ISBN 0-313-33438-2. (2006).

[6] Royal Society of Chemistry. "Visual Elements: Group 1-The Alkali Metals", Visual Elements. Royal Society of Chemistry Retrieved 13. (2012A).

[7] Butterman, W. C., Brooks, W. E. and Reese, Jr., R. G. "Mineral Commodity Profile: Cesium. USGS, Science for a changing world. United States Geological Survey", By CRC Press LLC. Boca Raton London New York Washington, D.C. (2005).

[8] Royal Society of Chemistry. "Visual Elements: Group 2-The Alkaline Earth Metals", Visual Elements. Royal Society of Chemistry. Retrieved 13 January (2012B).

[9] NCCI, NGO Coordination Committee for IRAQ. "Sulaymaniyah Governorate Profile", Available at: http://www.ncciraq.org/images/infobygov/NCCI_Sulaymaniyah_Governorate_Profile.pdf. (2015).

[10] Qadir, K. S. "Study of Erodibility of Soils in Iraqi Kurdistan Region", M. Sc. Thesis submitted to the council of the College of Agriculture, University of Sulaimani in Soil Science -Soil Conservation. Iraqi Kurdistan Region (IKR). (2001).

[11] Majid, S. N., Rashid, K. A and Karim, T. H. "Relative Contribution of Clay and Organic Fraction to the Cation Exchange Capacity of Northern Iraqi soils", Zanko, the Scientific Journal of Salahaddin University, Vol. 4, No.1, (1991).

[12] Gupta, P. K. "Soil, plant, water and fertilizer analysis", Fourth Edition. Agrobios, India. (2004).

[13] Jaiswal, P. C. "Soil, Plant and water Analysis", Kalyani Publishers. Ludhiana, New Delhi-Noida (U.P.) Hyderabad-Chennal-Kolkata-Cuttack. (2004).

[14] Black, C., A., Evans, D. D., White, J. L., Ensminger, L. E., Clark, F. E., and Dinauer, R. C. "Methods of Soil analysis. Part 1& Part 2. Chemical and Microbiological Properties", American Society of Agronomy, Publisher Madison, Wisconsin, USA. (1965).

[15] International Organization for Standardization. "Soil quality extraction of trace elements soluble in aqua regia", ISO 11466:1995(E). ISO, Geneva. Cited from Pueyo, M., Sastre, J., Hernandez, E., Vidal, M., Lopez-Sanchez, J. F., and Rauret, G. (2003). Prediction of Trace Element Mobility in Contaminated Soils by Sequential Extraction. J. Environmental Quality Vol. 32, pp. 2054-2066, (2003).

[16] Abdi, H. and Williams, L. J. "Principal component analysis". Overview. Volume 2, July/August. John Wiley & Sons, Inc.WIREs Comp Stat Vol. 2, pp. 433–459, (2010).

[17] Schoeneberger, P. J., Wysocki, D. A., Benham, E. C. and Broderson, W. D. "Field book for describing and sampling soils". Version 2.0 Natural Resources Conservation Service, National Soil Survey Center, Lincoln N E. (2002).

[18] Ruellan, A. "Morphology and distribution of calcareous soils in Mediterranean and desert regions", VP. FAO; FAO/UNDP Regional Seminar on Reclamation and Management of Calcareous Soils, Cairo (Egypt), 27 Nov - 2 Dec 1972. pp. 31, (1972).

[19] Grisso, R. B., Allley, M., Wysor, W. G. and Holshouser, D. "Precision Farming Tools: Soil Electrical Conductivity". Produced by Communications and Marketing, College of Agriculture and Life Sciences, Virginia Polytechnic Institute and State University. (2009).

[20] Bonn, B. A. "Interactions of a soil humic acid with alkali metal cations and alkaline earth metal cations", A thesis submitted to the faculty of the Oregon Graduate Institute of Science & Technology in partial fulfillment of the requirements for the degree of Doctor of Philosophy in Environmental Science and Engineering. Portland, and Hillsboro, Oregon, USA. (1992).

[21] Majid, S. N. "Valuation of ambient air pollution: a study of some urban areas in Sulaimani city and its surrounding/Kurdistan Region of Iraq", A Dissertation Submitted to the Council of Agricultural Faculty/ Sulaimani University in partial fulfillment for the Degree of Doctor of Philosophy in Environmental Pollution (Air Pollution). Regional Government of Iraqi Kurdistan. (2011).

[22] Sheikh-Abdullah, S. M. "Effect of plant coverage on transformation of mica to an expandable mineral in some forest soils of Kurdistan region/Iraq". A Dissertation Submitted to the Council of Agricultural Faculty/ Sulaimani University in partial fulfillment for the Degree of Doctor of Philosophy in Agriculture Science (Soil Chemistry and Mineralogy). Regional Government of Iraqi Kurdistan. (2012).

[23] Starova, N. V. "Environmental Problems and Principles of Their Solution by the Example of Southern Urals", Ed. Nauka, Moscow, Russian. (2003).

[24] Asylbaev, I. G., and Khabirov, I. K. "The Contents of Alkali and Alkaline Earth Metals in Soils of the Southern Cis-Ural Region", Eurasian Soil Science, Vol. 49, No. 1, pp. 24-32, (2016).

[25] Prusty, B. A. K., Chandra, R. and Azeez, P. A. "Temporal variation and distribution of selected alkali and alkaline earth metals in the sediment of a monsoonal wetland in India", PSP Vol. 18,No. 6, Fresenius Environmental Bulletin. (2009).

[26] Oldham, L. "Potassium in Mississippi Soils", Mississippi State University Extension Service, cooperating with U.S. Department of Agriculture. Published in furtherance of Acts of Congress, May 8 and June 30, 1914. Available at: http://msucares.com/pubs/infosheets/is0894.pdf. (2015).

[27] Prusty, B. A. K. and Azeez, P. A. "Vertical distribution of alkali and alkaline earth metals in the soil profile of a wetland–terrestrial ecosystem complex in India", Australian Journal of Soil Research, Vol. 45, pp. 533–542, (2007).

[28] Godunova, E. I., Chizhikova, N. P. and Shkabarda, S. N. "Natural reserves of magnesium in Stavropol Upland at different levels of anthropogenic impact on the agrolandscape", Dostizh. Nauki Tekh. Agroprom. Kompl., No. 4, 9-11, (2014).

[29] Shacklette, H. T. and Boerngen J. G. "Element Concentrations in Soils and Other Surficial Materials of the Conterminous United States", U.S. Geological Survey Professional Paper 1270 An account of the concentrations of 50 chemical elements in samples of soils and other regolith. United States Government Printing Office, Washington. (1984).

[30] Ropp, R. C. "Encyclopedia of the Alkaline Earth Compounds. Chapter 1 – The Alkaline Earths as Metals", Pages 1-23. Elsevier. Available at; http://dx.doi.org/10.1016/B978-0-444-59550-8.00001-6. (2013).

[31] Dobrotvorskaya, N. I. and Sememdyaeva, N. V. "Stable strontium in forest steppe and steppe landscapes of Western Siberia", Eurasian Soil Sci. Vol. 34, No. 2, pp. 169–179, (2001).

[32] Asylbaev, I. G. and Khabirov, I. K. "Concentration of Chemical Elements in Soils and Mminerals of the Republic of Bashkortostan", Vestn. Ul’yanovsk. Gos. Sel’skokhoz. Akad., No. 2, pp. 11-16, (2003).

[33] Sahai, N., Carroll, S. A., Roberts, S. O. and Day, P. A. "X-ray absorption spectroscopy of strontium (II) coordination: II. Sorption and precipitation at kaolinite, amorphous silica, and goethite surfaces", Journal of Colloid and Interface Science, Vol. 222, pp. 198-212, (2000).

[34] Parkman, R. H., Charnock, J. M., Livens, F. R. and Vaughan, D. J. "A study of the interaction of strontium ions in aqueous solution with the surfaces of calcite and kaolinite", Geochimica et Cosmo-chimica Acta, Vol. 62, No. 9, pp. 1481-1492, (1998).

[35] Glinka, N. L. "General chemistry, Leningrad: Khimiya (Chemistry in Russian)". Publishing House 1976, pp.185. Cited in: Asylbaev, I. G., and Khabirov, I. K. (2016). The Contents of Alkali and Alkaline Earth Metals in Soils of the Southern Cis-Ural Region. Eurasian Soil Science, Vol. 49, No. 1, pp. 24-32.

[36] Ong, G. H., Yap, C. K., Mahmood, M., Tan, S. G. and and Hamzah, S. "Barium Levels in Soils and Centella asiatica", Tropical Life Sciences Research, Vol. 24, No. 1, pp. 55-70, (2013).