Synthesis and Characterization of Novel Biological Mixed Organometallic Chromium (III) Complex of Potential Allyl-Sulfur Compounds of Garlic, Allicin

M. A. Andullah, & D. I. Tofiq

College of Science, University of Sulaimani

From the readily acid and base hydrolysis (pH - dependence) of loosely Cr - S bond of bis (L- cysteinato)chromium (III) complexes, a biological mixed organometallic
- werner chromium complex, of trans - bis [(n3) s - allyl mercapto cysteinato ] chromium (III) hydroxide, has been synthesized via intermolecular insertion reaction of allyl sulfenic acid, which was extracted and isolated from natural garlic. This complex was characterized using IR, NMR, UV -Visible spectroscopic techniques and elemental analysis. Also biological activity of the prepared cormplex was tested in vitro.

Keyword :- Chromium (III), Organometallic, Garlic. Allicin.


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